Novel Design of Tunable Organic Clay Mimic Structures Based on the Connection of One-Dimensional Supramolecular Synthons

Novel Design of Tunable Organic Clay Mimic Structures Based on the Connection of One-Dimensional Supramolecular Synthons
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DOI:
10.1021/cg0600851
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发表时间:
2006-05
影响因子:
3.8
通讯作者:
Tetsuharu Yuge;M. Miyata;N. Tohnai
Tetsuharu Yuge;M. Miyata;N. Tohnai
中科院分区:
化学2区
文献类型:
--
作者:
Tetsuharu Yuge;M. Miyata;N. Tohnai

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我们报道了具有一维超分子合成子和芳香族结构的可调有机粘土模拟结构的设计和构造。通过将强健的一维合成子与二元酸连接起来,我们成功地将Tecton引入了层基序。因此,这些结构使我们能够通过只改变所使用的二元酸来控制分子的间隔和合成子的方向。
We report the design and construction of tunable organic clay mimic structures with one-dimensional supramolecular synthons and aromatic tectons. By connecting the robust one-dimensional synthons with dicarboxylic acids, we succeeded in introducing the tectons into layer motifs. Therefore, the structures enable us to control the intervals of the molecules and the direction of the synthons by just varying the dicarboxylic acids employed.