Efficient visible light-mediated cross-dehydrogenative coupling reactions of tertiary amines catalyzed by a polymer-immobilized iridium-based photocatalyst

Efficient visible light-mediated cross-dehydrogenative coupling reactions of tertiary amines catalyzed by a polymer-immobilized iridium-based photocatalyst
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DOI:
10.1039/c4gc00058g
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发表时间:
2014-04
期刊:
影响因子:
9.8
通讯作者:
Woo‐Jin Yoo;S. Kobayashi
Woo‐Jin Yoo;S. Kobayashi
中科院分区:
化学1区
文献类型:
--
作者:
Woo‐Jin Yoo;S. Kobayashi

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采用自由基聚合法固定化了一种铱基非均相光催化剂,并对其在可见光照射下对n -芳基四氢异喹啉需氧膦化反应的催化活性进行了评价。
The immobilization of an iridium-based heterogeneous photocatalyst via a radical polymerization process is described, and its catalytic activity was evaluated for the aerobic phosphonylation reaction of N-aryl tetrahydroisoquinolines under visible light irradiation.