Handbook of organopalladium chemistry for organic synthesis
Handbook of organopalladium chemistry for organic synthesis
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DOI：
10.1002/0471212466
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发表时间：
2002-07
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影响因子：
--
通讯作者：
E. Negishi
中科院分区：
文献类型：
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作者：
E. Negishi
前言。贡献者。简介和背景。有机钯化学的历史背景钯的基本性质以及钯及其配合物的反应模式。钯化合物：化学计量制备、原位生成以及一些物理和化学特性。第二部分的背景。不含碳-钯键的 Pd(0) 和 Pd(II) 化合物。含有 Pd(0) 和 Pd(II) 的有机钯化合物。含有 Pd(I)、Pd(III) 或 Pd(IV) 的钯络合物。涉及还原消除的钯催化反应。第三部分的背景。钯催化的碳-碳交叉偶联。钯催化的碳-氢和碳-杂原子偶联。涉及碳钯化的钯催化反应。第四部分的背景。 Heck 反应（通过碳钯化-脱氢钯化进行烯烃取代）和相关的碳钯化反应。钯催化的炔烃和 1,1-二取代烯烃的串联和级联碳钯化。烯烃、炔烃、二烯和其他化合物的烯丙基钯化和相关反应。通过炔基钯化-还原消除进行炔基取代。通过加法-消除法进行芳烃取代。艾伦的碳钯化。通过碳钯化合成天然产物。钯-卡宾（和卡宾）配合物的环丙烷化和其他反应。通过环丙烷和环丙烯进行碳钯化。钯催化的碳锌化。涉及配体亲核攻击的钯催化反应。第五部分的背景：涉及烯丙基钯、炔丙基钯和相关衍生物的钯催化亲核取代。涉及对钯-烯烃、钯-炔和相关衍生物的配体进行亲核攻击的钯催化反应。钯催化的羰基化和其他涉及迁移插入的相关反应。第六部分的背景。涉及一氧化碳和相关衍生物的烷基、芳基、烯基和炔基钯衍生物的迁移插入反应。涉及一氧化碳和相关衍生物的烯丙基、炔丙基和烯基钯衍生物的迁移插入反应。酰基钯化和相关加成反应。酰基钯衍生物的其他反应。通过钯催化羰基化合成天然产物。钯催化的羰基氧化。通过钯催化异腈连续迁移插入合成低聚物和聚合物材料。通过氢化钯化、金属钯化和其他相关的顺式加成反应进行催化加氢和其他钯催化反应，无需碳-碳键形成或裂解。第七部分的背景。钯催化氢化。钯催化的烯烃、炔烃和相关化合物的异构化，无需骨架重排。钯催化的加氢金属化。金属钯化。钯催化的 X-Pd 键顺式加成反应（X = 第 15、16 和 17 族元素）。前面部分中尚未讨论的钯催化氧化反应。第八部分的背景。通过 Pd(II) 和 Pd(IV) 配合物的还原消除进行氧化。钯催化或通过 1,2- 或 1,4- 消除促进氧化。其他各种钯催化或促进的氧化反应。钯催化的重排和其他杂项反应。第九部分的背景。钯催化的重排反应。有机钯化学的技术发展。钯水溶液催化。固定在聚合物载体上的钯催化剂。组合化学中的有机钯反应。参考。有关钯和有机钯化学参考文献的一般指南。书籍（专着）。评论和帐户（截至 1999 年 9 月）。主题索引。
PREFACE. CONTRIBUTORS. INTRODUCTION AND BACKGROUND. Historical Background of Organopalladium Chemistry Fundamental Properties of Palladium and Patterns of the Reactions of Palladium and Its Complexes. PALLADIUM COMPOUNDS: STOICHIOMETRIC PREPARATION, IN SITU GENERATION, AND SOME PHYSICAL AND CHEMICAL PROPERTIES. Background for Part II. Pd(0) and Pd(II) Compounds Without Carbon-Palladium Bonds. Organopalladium Compounds Containing Pd(0) and Pd(II). Palladium Complexes Containing Pd(I), Pd(III), or Pd(IV). PALLADIUM-CATALYZED REACTIONS INVOLVING REDUCTIVE ELIMINATION. Background for Part III. Palladium-Catalyzed Carbon-Carbon Cross-Coupling. Palladium-Catalyzed Carbon-Hydrogen and Carbon- Heteroatom Coupling. PALLADIUM-CATALYZED REACTIONS INVOLVING CARBOPALLADATION. Background for Part IV. The Heck Reaction (Alkene Substitution via Carbopalladation- Dehydropalladation) and Related Carbopalladation Reactions. Palladium-Catalyzed Tandem and Cascade Carbopalladation of Alkynes and 1,1-Disubstituted Alkenes. Allylpalladation and Related Reactions of Alkenes, Alkynes, Dienes, and Other -Compounds. Alkynyl Substitution via Alkynylpalladation-Reductive Elimination. Arene Substitution via Addition-Elimination. Carbopalladation of Allenes. Synthesis of Natural Products via Carbopalladation. Cyclopropanation and Other Reactions of Palladium-Carbene (and Carbyne) Complexes. Carbopalladation via Palladacyclopropanes and Palladacyclopropenes. Palladium-Catalyzed Carbozincation. PALLADIUM-CATALYZED REACTIONS INVOLVING NUCLEOPHILIC ATTACK ON LIGANDS. Background for Part V. Palladium-Catalyzed Nucleophilic Substitution Involving Allylpalladium, Propargylpalladium, and Related Derivatives. Palladium-Catalyzed Reactions Involving Nucleophilic Attack on -Ligands of Palladium-Alkene, Palladium-Alkyne, and Related Derivatives. PALLADIUM-CATALYZED CARBONYLATION AND OTHER RELATED REACTIONS INVOLVING MIGRATORY INSERTION. Background for Part VI. Migratory Insertion Reactions of Alkyl-, Aryl-, Alkenyl-, and Alkynylpalladium Derivatives Involving Carbon Monoxide and Related Derivatives. Migratory Insertion Reactions of Allyl, Propargyl, and Allenylpalladium Derivatives Involving Carbon Monoxide and Related Derivatives. Acylpalladation and Related Addition Reactions. Other Reactions of Acylpalladium Derivatives. Synthesis of Natural Products via Palladium-Catalyzed Carbonylation. Palladium-Catalyzed Carbonylative Oxidation. Synthesis of Oligomeric and Polymeric Materials via Palladium-Catalyzed Successive Migratory Insertion of Isonitriles. CATALYTIC HYDROGENATION AND OTHER PALLADIUM-CATALYZED REACTIONS VIA HYDROPALLADATION, METALLOPALLADATION, AND OTHER RELATED SYN ADDITION REACTIONS WITHOUT CARBON-CARBON BOND FORMATION OR CLEAVAGE. Background for Part VII. Palladium-Catalyzed Hydrogenation. Palladium-Catalyzed Isomerization of Alkenes, Alkynes, and Related Compounds without Skeletal Rearrangements. Palladium-Catalyzed Hydrometallation. Metallopalladation. Palladium-Catalyzed Syn-Addition Reactions of X-Pd Bonds (X = Group 15, 16, and 17 Elements). PALLADIUM-CATALYZED OXIDATION REACTIONS THAT HAVE NOT BEEN DISCUSSED IN EARLIER PARTS. Background for Part VIII. Oxidation via Reductive Elimination of Pd(II) and Pd(IV) Complexes. Palladium-Catalyzed or -Promoted Oxidation via 1,2- or 1,4-Elimination. Other Miscellaneous Palladium-Catalyzed or -Promoted Oxidation Reactions. REARRANGEMENT AND OTHER MISCELLANEOUS REACTIONS CATALYZED BY PALLADIUM. Background for Part IX. Rearrangement Reactions Catalyzed by Palladium. TECHNOLOGICAL DEVELOPMENTS IN ORGANOPALLADIUM CHEMISTRY. Aqueous Palladium Catalysis. Palladium Catalysts Immobilized on Polymeric Supports. Organopalladium Reactions in Combinatorial Chemistry. REFERENCES. General Guidelines on References Pertaining to Palladium and Organopalladium Chemistry. Books (Monographs). Reviews and Accounts (as of September 1999). SUBJECT INDEX.