Ashura Particles: Experimental and Theoretical Approaches for Creating Phase-Separated Structures of Ternary Blended Polymers in Three-Dimensionally Confined Spaces

Ashura Particles: Experimental and Theoretical Approaches for Creating Phase-Separated Structures of Ternary Blended Polymers in Three-Dimensionally Confined Spaces
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阿舒拉粒子:在三维有限空间中创建三元共混聚合物相分离结构的实验和理论方法

DOI:
10.1021/acsomega.9b00991
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发表时间:
2019
期刊:
影响因子:
4.1
通讯作者:
Hiroshi Yabu
Hiroshi Yabu
中科院分区:
化学3区
文献类型:
--
作者:
Yutaro Hirai;Edgar Avalos;Takashi Teramoto;Yasumasa Nishiura;Hiroshi Yabu

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在二元和三元聚合物共混颗粒中发现了独特的形态,包括阿修罗型相分离,其在颗粒表面上具有三种不同的聚合物组分。根据共混聚合物的表面张力讨论了二元聚合物共混粒子中相分离结构的形态。通过对二元聚合物共混粒子的研究,实现了基于聚合物组合的三元聚合物共混粒子的结构控制。基于Cahn-Hilliard方程的理论方法给出了与实验结果相同的形态。这项工作开辟了通过控制理论模拟预测的形态来创造具有复杂纳米结构的聚合物颗粒的道路。
Unique morphologies were found in binary and ternary polymer blended particles, including Ashura-type phase separation, which has three different polymer components on the particle surface. The morphologies of phase-separated structures in the binary polymer blended particles are discussed in terms of the surface tensions of the blended polymers. Structural control of ternary polymer blended particles was achieved based on the combination of polymers by examining binary polymer blended particles. A theoretical approach based on the Cahn–Hilliard equations gives identical morphologies with the experimental results. This work opens the way to creating polymer particles with sophisticated nanostructures by controlling their morphologies as predicted by theoretical simulations.
共聚物均聚物混合物的三维形态
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