Charge neutrality levels, barrier heights, and band offsets at polar AlGaN

Charge neutrality levels, barrier heights, and band offsets at polar AlGaN
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DOI:
10.1063/1.4930026
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发表时间:
2015-09
影响因子:
4
通讯作者:
P. Reddy;I. Bryan;Z. Bryan;J. Tweedie;S. Washiyama;R. Kirste;S. Mita;R. Collazo;Z. Sitar
P. Reddy;I. Bryan;Z. Bryan;J. Tweedie;S. Washiyama;R. Kirste;S. Mita;R. Collazo;Z. Sitar
中科院分区:
物理与天体物理2区
文献类型:
--
作者:
P. Reddy;I. Bryan;Z. Bryan;J. Tweedie;S. Washiyama;R. Kirste;S. Mita;R. Collazo;Z. Sitar

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In this work, the Fermi level and band alignment at c-plane surfaces and interfaces of AlGaN thin films grown on sapphire and native single crystalline AlN substrates were analyzed via x-ray photoelectron spectroscopy. The dependence of charge neutrality level (CNL) on Al composition is found to be linear with n-type Schottky barrier heights (Φbn) exhibiting an overall quadratic behavior due to bandgap bowing. A general theoretical expression for Schottky barrier height on AlGaN is determined as a function of Al composition and metal electronegativity utilizing the interface induced gap states (IFIGS) model and is corroborated with current-voltage (I-V) characterization on Ni-based Schottky diodes. The measured CNLs were used to determine the conduction and valence band offsets in AlGaN hetero-junctions according to the IFIGS and were found to be split approximately 2/3 and 1/3 of the bandgap, respectively, at interfaces with AlGaN having comparable Al and Ga concentrations. Nonlinearities in Φbn result i...