Hybridized Microcrystals Composed of Metal Fine Particles and π-Conjugated Organic Microcrystals
Hybridized Microcrystals Composed of Metal Fine Particles and π-Conjugated Organic Microcrystals
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金属微粒与π共轭有机微晶的杂化微晶
DOI：
10.1143/jjap.40.l1129
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发表时间：
2001
影响因子：
1.5
通讯作者：
H. Nakanishi
中科院分区：
文献类型：
--
作者：
A. Masuhara;H. Kasai;S. Okada;H. Oikawa;M. Terauchi;Michiyoshi Tanaka;H. Nakanishi
采用共沉淀法成功地制备了聚丁二炔微晶与银微粒的杂化微晶，并对其杂化结构和光学性质进行了研究。首次从实验上揭示了杂化微晶体中金属微粒的核畴与聚丁二炔的壳层发生光电相互作用，产生与原化合物不同的电子态。
We have successfully prepared hybridized microcrystals composed of polydiacetylene microcrystals and silver fine particles by means of the co-reprecipitation method, and investigated their hybridized structure and optical properties. It was revealed experimentally for the first time that the core domain of metal fine particles may interact optoelectronically with the shell layer of polydiacetylene in the hybridized microcrystals to give different electronic states from those of the original compounds.