Boron Fluoride-Alcohol Alkylations. III. Stereochemistry of Alkylation of Benzene with 2-Propanol-1-d31
Boron Fluoride-Alcohol Alkylations. III. Stereochemistry of Alkylation of Benzene with 2-Propanol-1-d31
复制标题
氟化硼-醇烷基化。
DOI：
10.1021/ja00949a047
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发表时间：
1965
影响因子：
15
通讯作者：
P. Stang
中科院分区：
文献类型：
--
作者：
A. Streitwieser;P. Stang
Although the kinetics of the presteady state and steady state of the hydrolysis of the nonspecific substrate,/i-nitrophenyl acetate, by-chy mo trypsin2, 3 and trypsin4 have been delineated, a complete kinetic analysis of this kind had not been carried out for the corresponding hydrolysis of a specific substrate of these enzymes. This paper reports the first such re-action, the trypsin-catalyzed hydrolysis of p-nitro-phenyl--benzyloxycarbonyl-L-lysinate hydrochloride, which can be analyzed in terms of eq. 1 whose symbols
