Hydrogenation of Chlorosilanes by NaBH4
Hydrogenation of Chlorosilanes by NaBH4
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DOI：
10.1246/cl.160808
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发表时间：
2016-10
影响因子：
1.6
通讯作者：
Masaki Ito;Masumi Itazaki;A. Takashi;H. Nakazawa
中科院分区：
文献类型：
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作者：
Masaki Ito;Masumi Itazaki;A. Takashi;H. Nakazawa
氯硅烷在乙腈中用一种安全易操作的试剂氢化钠进行加氢反应。该反应将有机硅烷中的硅-氯部分(S)转化为硅-氢部分(S)，而不需要在硅试剂的烷基上加氢氰基、氯基和醛基。此外，Si-Cl/Si-H交换反应也适用于无Si-Si键断裂的二氯二硅烷。
Hydrogenation of chlorosilane was achieved in acetonitrile using NaBH4, a safe and easy-to-handle reagent. This reaction converted Si–Cl portion(s) in organosilanes into Si–H portion(s) without hydrogenation of cyano, chloro, and aldehyde groups on an alkyl substituent of the Si reagents. In addition, the Si–Cl/Si–H exchange reaction was applicable to dichlorodisilane without Si–Si bond cleavage.