Relaxations in heterolanthanide dinuclear single-molecule magnets

Relaxations in heterolanthanide dinuclear single-molecule magnets
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异镧系双核单分子磁体的弛豫

DOI:
10.1039/c2cc37036k
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发表时间:
2013-01-01
影响因子:
4.9
通讯作者:
Tong, Ming-Liang
Tong, Ming-Liang
中科院分区:
化学2区
文献类型:
--
作者:
Leng, Ji-Dong;Liu, Jun-Liang;Tong, Ming-Liang

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异自旋双核配合物[Dy 0.87 Yb 1.13(H(2)cht)(2)Cl-4(H2O)(MeCN)]中心点MeCN显示弛豫势垒相对于同自旋Dy-2和Yb-2同构配合物中观察到的势垒的移动。后两种化合物的慢弛豫的起源是由从头计算阐明。
A heterospin dinuclear complex [Dy0.87Yb1.13(H(2)cht)(2)Cl-4(H2O)(MeCN)]center dot MeCN shows shifts of the relaxation barriers with respect to the barriers observed in homospin Dy-2 and Yb-2 isostructural complexes. The origin of slow relaxation in the latter two compounds was elucidated by ab initio calculations.