Efficient polymer photovoltaic cells using solution-processed MoO3 as anode buffer layer

Efficient polymer photovoltaic cells using solution-processed MoO3 as anode buffer layer
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使用溶液处理的MoO3作为阳极缓冲层的高效聚合物光伏电池

DOI:
10.1016/j.solmat.2010.01.004
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发表时间:
2010-05-01
影响因子:
6.9
通讯作者:
Xie, Zhiyuan
Xie, Zhiyuan
中科院分区:
材料科学2区
文献类型:
--
作者:
Liu, Fengmin;Shao, Shuyan;Xie, Zhiyuan

文献摘要

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以溶液处理的氧化钼(MoO_3)为阳极缓冲层,制备了基于区域规整聚3-己基噻吩基(P3HT)富勒烯衍生物[6,6]-苯基-C-61丁酸甲酯(PC61BM)复合材料的高效光伏电池。研究了溶液处理的MoO_3阳极缓冲层对P3HT:PCBM光伏电池性能的影响,并与具有不同阳极缓冲层的光伏电池进行了比较,其中包括水溶性poly(ethylenedioxythiophene):poly(styrenesulfonate)(PEDOT:PSS)和热蒸发MoO_3。研究发现,采用溶液处理的MoO_3阳极缓冲层的光伏电池的性能与采用PEDOT:PSS或热蒸发MoO_3作为阳极缓冲层的光伏电池的性能相当或更高。在AM1.5G 100 mW/cm(2)光照下,采用溶液处理的MoO_3阳极缓冲层的光伏电池的功率转换效率达到3.14%。(C)2010爱思唯尔B.V.保留所有权利。
Efficient photovoltaic (PV) cells based on regioregular poly(3-hexylthiophene) (P3HT):fullerene derivative [6,6]-phenyl-C-61 butyric acid methyl ester (PC61BM) composites have been fabricated by using solution-processed molybdenum oxide (MoO3) as an anode buffer layer. The influence of solution-processed MoO3 anode buffer layer on the device performance of P3HT:PCBM PV cells is investigated as compared to the PV cells with different anode buffer layers including water-soluble poly(ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) and the thermally evaporated MoO3. It is found that the performance of the PV cell with solution-processed MoO3 anode buffer layer is comparable or higher than the devices using PEDOT:PSS or thermally evaporated MoO3 as the anode buffer layer. The power conversion efficiency of PV cell with solution-processed MoO3 anode buffer layer reaches 3.14% under AM1.5G 100 mW/cm(2) illumination. (C) 2010 Elsevier B.V. All rights reserved.