Synthesis of copolymer via hybrid polymerization: From random to well-defined sequence

Synthesis of copolymer via hybrid polymerization: From random to well-defined sequence
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通过杂化聚合合成共聚物:从随机到明确的序列

DOI:
10.1016/j.eurpolymj.2019.109374
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发表时间:
2020-01
影响因子:
6
通讯作者:
You Ye-Zi
You Ye-Zi
中科院分区:
化学2区
文献类型:
--
作者:
Xia Lei;Zhang Ze;Hong Chun-Yan;You Ye-Zi

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合成具有可控甚至精确序列结构的共聚物,如生物大分子,一直是高分子科学中的一个严峻挑战。近年来,杂化聚合已成为制备不同序列结构共聚物的一种备受关注的合成方法。在这篇综述中,我们将讨论这一方法,并重点讨论获得的共聚物的序列结构,它经历了一个从产生随机不可控序列到构建序列控制共聚物甚至按需序列共聚物的过程。
Synthesizing copolymers with controlled, and even precise sequence structures, such as biological macromolecules, has been a serious challenge in polymer science. Recently, hybrid polymerization has become an attention-getting synthetic method for preparing copolymers with different sequence structures. In this review, we will discuss this method and focus on the sequence structure of the obtained copolymers, which have gone through a process from producing random uncontrollable sequences, to constructing sequence-controlled copolymers and even sequence-on-demand copolymers.
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