A polyethylene-glycol-functionalized ring-like isopolymolybdate cluster
A polyethylene-glycol-functionalized ring-like isopolymolybdate cluster
复制标题
聚乙二醇功能化环状异聚钼酸盐簇
DOI:
10.1016/j.ica.2008.10.035
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发表时间:
2009-05
影响因子:
2.8
通讯作者:
Z. M. Zhang
中科院分区:
文献类型:
--
作者:
E. B. Wang;J. Ma;Y. G. Li;Q. Wu;Z. M. Zhang
A new organic–inorganic hybrid compound, Na6[HO(CH2CH2O)4H]3{Mo36O108(H2O)14(OH)6[HO(CH2CH2O)3H]2}·∼75H2O (1) has been obtained in polyethylene glycol (PEG)/H2O system with a good yield, and characterized by element analysis, IR, UV, TG,13C NMR spectroscopy, electrochemistry and X-ray single crystal diffraction analysis. Compound 1 consists of the {Mo36} clusters as the structural motif covalently decorated by PEG fragments. Such hybrid polyoxoanions are linked by Na+counter-cations, leading to one-dimensional chains. The adjacent chains are closely packed together into a three-dimensional supramolecular framework via extensive H-bonding interactions among polyoxoanions and the isolated water molecules.
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影响因子:
4.9
作者:
D. Hagrman;P. Zapf;J. Zubieta
通讯作者:
D. Hagrman;P. Zapf;J. Zubieta
影响因子:
3.8
作者:
Guang Liu;Yongge Wei;Q. Yu;Qun Liu;Shiwei Zhang
通讯作者:
Guang Liu;Yongge Wei;Q. Yu;Qun Liu;Shiwei Zhang
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M. Sadakane;M. Dickman;Michael T. Pope
影响因子:
64.8
作者:
Li, H;Eddaoudi, M;Yaghi, OM
通讯作者:
Yaghi, OM
影响因子:
4.9
作者:
C. Ritchie;E. Burkholder;D. Long;D. Adam;P. Kögerler;L. Cronin
通讯作者:
C. Ritchie;E. Burkholder;D. Long;D. Adam;P. Kögerler;L. Cronin