A polyethylene-glycol-functionalized ring-like isopolymolybdate cluster

A polyethylene-glycol-functionalized ring-like isopolymolybdate cluster
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聚乙二醇功能化环状异聚钼酸盐簇

DOI:
10.1016/j.ica.2008.10.035
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发表时间:
2009-05
影响因子:
2.8
通讯作者:
Z. M. Zhang
Z. M. Zhang
中科院分区:
化学3区
文献类型:
--
作者:
E. B. Wang;J. Ma;Y. G. Li;Q. Wu;Z. M. Zhang

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A new organic–inorganic hybrid compound, Na6[HO(CH2CH2O)4H]3{Mo36O108(H2O)14(OH)6[HO(CH2CH2O)3H]2}·∼75H2O (1) has been obtained in polyethylene glycol (PEG)/H2O system with a good yield, and characterized by element analysis, IR, UV, TG,13C NMR spectroscopy, electrochemistry and X-ray single crystal diffraction analysis. Compound 1 consists of the {Mo36} clusters as the structural motif covalently decorated by PEG fragments. Such hybrid polyoxoanions are linked by Na+counter-cations, leading to one-dimensional chains. The adjacent chains are closely packed together into a three-dimensional supramolecular framework via extensive H-bonding interactions among polyoxoanions and the isolated water molecules.
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