New insight on ancient cosmetic preparation by synchrotron-based infrared microscopy

New insight on ancient cosmetic preparation by synchrotron-based infrared microscopy
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DOI:
10.1016/j.aca.2005.07.067
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发表时间:
2005-11-30
影响因子:
6.2
通讯作者:
Walter, P
Walter, P
中科院分区:
化学1区
文献类型:
--
作者:
Cotte, M;Dumas, P;Walter, P

文献摘要

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同步加速器红外显微光谱非常适合分析考古化妆品的小颗粒。该样品来自 33 世纪前的埃及化妆品遗迹。由于这种基于同步加速器的显微光谱工具实现了高光谱质量和高横向分辨率,获得了对样品有机和矿物成分的组成和空间位置的新见解。对五种不同的颗粒进行了分析,并得出了类似的结果:核心富含脂肪,并被矿物相包围。在两个颗粒中,棕榈酸铅被明确确定为主要成分。亚磷矿 (Pb2CO3Cl2) 是一种在水溶液中合成的铅盐,也位于颗粒表面附近的区域。 (c) 2005 Elsevier B.V. 保留所有权利。
Synchrotron IR micro-spectroscopy is appropriately suited to the analysis of small particles of archaeological cosmetics. The sample originates from a 33 centuries old Egyptian cosmetic remain. Thanks to the high spectral quality and high lateral resolution achieved by this synchrotron-based microspectroscopic tool, new insights into the composition and spatial location of both organic and mineral components of the sample were obtained. Five different particles were analyzed and delivered similar findings: the core is fat rich, and surrounded with a mineral phase. In two particles, lead palmitate was clearly identified as a major component. Phosgenite (Pb2CO3Cl2), a lead salt synthesized in aqueous solution, was also located in region near the surface of the particles. (c) 2005 Elsevier B.V. All rights reserved.