Zinc adsorption on Na-rectorite and effect of static magnetic field on the adsorption

Zinc adsorption on Na-rectorite and effect of static magnetic field on the adsorption
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DOI:
10.1016/j.clay.2004.09.001
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发表时间:
2005-02
影响因子:
5.6
通讯作者:
Gaoke Zhang;Y. Liu;Yi-Kuan Xie;Xia Yang;Bo Hu;S. Ouyang;Hanxing Liu;Huiyan Wang
Gaoke Zhang;Y. Liu;Yi-Kuan Xie;Xia Yang;Bo Hu;S. Ouyang;Hanxing Liu;Huiyan Wang
中科院分区:
地球科学2区
文献类型:
--
作者:
Gaoke Zhang;Y. Liu;Yi-Kuan Xie;Xia Yang;Bo Hu;S. Ouyang;Hanxing Liu;Huiyan Wang

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累托石是一种稀有粘土矿物。本文研究了Zn ~(2+)在钠基累托石上的吸附及静磁场对吸附的影响。结果表明:(1)Na型累托石对Zn ~(2+)的吸附在第一个小时内达到表观平衡,(2)Na型累托石对Zn ~(2+)的吸附量在pH 4 ~ 6之间达到最大值;(3)磁处理提高了无Zn ~(2+)存在时钠累托石分散体的zeta电位,降低了Zn ~(2+)存在时的zeta电位磁场处理促进了累托石对Zn ~(2+)的吸附,特别是在低Zn ~(2+)浓度时;静磁场作用降低了含锌和不含锌的累托石分散液的pH值。探讨了静磁场作用下Na型累托石对Zn ~(2+)的吸附机理。
Rectorite is a kind of rare clay minerals. In this work, the sorption of Zn2+on Na-rectorite and the effects of static magnetic field on the sorption have been studied. The result from this study indicated that: (1) apparent equilibrium for the sorption of zinc onto Na-rectorite is attained within the first hour; (2) the maximum of the increment of Zn2+adsorbed by Na-rectorite is obtained between pH 4 and pH 6; (3) magnetic treatment enhances the zeta potential of Na-rectorite dispersions in the absence of Zn2+and reduces that of the dispersions in the presence of Zn2+; (4) magnetic treatment promotes the sorption of Zn2+onto Na-rectorite, especially at the low Zn2+concentration; (5) the effects of static magnetic field decrease the pH of Na-rectorite dispersions whether containing zinc or not. The mechanisms of static magnetic field on the sorption of Zn2+on Na-rectorite were discussed.