Solute Retention in Column Liquid Chromatography. III. Computer Optimization of Mobile-Phase Compositions: Program Window
Solute Retention in Column Liquid Chromatography. III. Computer Optimization of Mobile-Phase Compositions: Program Window
复制标题
柱液相色谱中的溶质保留。
DOI：
10.1080/01483918408073993
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发表时间：
1984
影响因子：
1.3
通讯作者：
R. Laub
中科院分区：
文献类型：
--
作者：
R. Laub
本文介绍了一个计算溶质保留值的程序，该程序仅从色谱测量中获得的数据计算溶质保留值（从而优化其分离条件）。预排序循环识别用户定义的最难分离因子Sf值内的相关（窗口图边界）溶质对。程序运行时间因此比先前使用的“蛮力”技术缩短了几个因素，其中在待优化的独立参数的每个值处考虑所有可能的对。为阵列保留的所需CPU空间也因此减少。该程序是为APPLE II Plus系统编写的;指出并讨论了与其他版本BASIC不兼容的语句。
Abstract A program is described that calculates solute retentions (thence optimized conditions for their separation) from data acquired solely from chromatographic measurements. A pre-sorting loop identifies the relevant (window-diagram boundary) pairs of solutes within a user-defined value of the most-difficult separation factor, Sf. The program run time is consequently shortened by several factors over previously-used “brute-force” techniques wherein all possible pairs are considered at each value of the independent parameter(s) to be optimized. The required CPU space reserved for arrays is thereby also diminished. The program was written for an APPLE II Plus system; statements not compatible with other versions of BASIC are pointed out and discussed.