Spontaneous formation of polymer nanoparticles with inner micro-phase separation structures

Spontaneous formation of polymer nanoparticles with inner micro-phase separation structures
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DOI:
10.1039/b800904j
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发表时间:
2008-01-01
期刊:
影响因子:
3.4
通讯作者:
Shimomura, Masatsugu
Shimomura, Masatsugu
中科院分区:
化学2区
文献类型:
--
作者:
Higuchi, Takeshi;Tajima, Atsunori;Shimomura, Masatsugu

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We demonstrate the preparation of particles with a variety of inner structures from block-copolymers and polymer blends by using a simple solvent evaporation process. One-directionally stacked or onion-like lamellar structures were formed from symmetric block-copolymers. Asymmetric block-copolymers formed cylindrical phase in nanoparticles. "Janus''-type particles were prepared from homopolymer blends. A network structure was formed in the homopolymer blend particles containing block-copolymers, which work as compatibilizers for homopolymer blends.