Iridabenzenes from iridacyclopentadienes: Unusual C-C bond formation between unsaturated hydrocarbyl ligands
Iridabenzenes from iridacyclopentadienes: Unusual C-C bond formation between unsaturated hydrocarbyl ligands
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DOI：
10.1021/om050529a
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发表时间：
2005-09-26
期刊：
影响因子：
2.8
通讯作者：
Eum, MS
中科院分区：
文献类型：
--
作者：
Chin, CS;Lee, H;Eum, MS
在炔基配体的β-碳质子化后，通过炔基配体的α-碳和相邻的1，3-丁二烯基配体的δ-碳之间的不寻常的C-C偶联来产生氮杂苯。
Iridabenzenes are produced by an unusual C-C coupling between the alpha-carbon of the alkynyl ligand and the delta-carbon of the neighboring 1,3-butadienyl ligand upon protonation of the beta-carbon of the alkynyl ligand.