Synthesis of Pentadecaphenylenes, Its Inclusion Properties, and Nanostructure Formation with C60
Synthesis of Pentadecaphenylenes, Its Inclusion Properties, and Nanostructure Formation with C60
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十五苯撑的合成、包合物性质以及 C60 纳米结构的形成
DOI：
10.1039/c3cc42922a
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发表时间：
2013
期刊：
影响因子：
--
通讯作者：
M. Iyoda
中科院分区：
文献类型：
--
作者：
M. J. Rahman;H. Shimizu;Y. Araki;H. Ikeda;M. Iyoda
以Lipshutz铜配合物为原料，通过电子转移氧化反应合成了十五苯撑大环化合物。十五亚苯基在溶液中自聚集形成凝胶。此外，它纳入C60在其空腔，产生纤维状包合物，显示出高的凝胶化能力，在苯中。
Synthesis of macrocyclic pentadecaphenylene was carried out via electron-transfer oxidation of the corresponding Lipshutz cuprate. Pentadecaphenylene self-aggregated in solution to form a gel. Furthermore, it incorporated C60 in its cavity to produce a fibrous inclusion complex which showed a high gelation ability in benzene.