Malyngamides M and N from the Hawaiian red alga Gracilaria coronopifolia

Malyngamides M and N from the Hawaiian red alga Gracilaria coronopifolia
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DOI:
10.1021/np970423n
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发表时间:
1998-01-01
影响因子:
5.1
通讯作者:
Hokama, Y
Hokama, Y
中科院分区:
生物学2区
文献类型:
--
作者:
Kan, Y;Fujita, T;Hokama, Y

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从夏威夷红藻Gracilaria coronopifolia中分离得到两个新的malynGamide,M和N(1,2)和malyngamide I乙酸酯(3)。我们的结果表明,三氨基甲酰胺N(2)是去乙酰氧基苯乙酰胺(5)的一个修正结构。用反八元规则推算出醋酸甘氨酰胺的绝对构型为3。
Two new malyngamides, M and N (1, 2), were isolated along with malyngamide I acetate (3) from the Hawaiian red alga Gracilaria coronopifolia. Our results suggest that malyngamide N (2) is a revised structure of deacetoxystylocheilamide (5). The absolute configuration of malyngamide I acetate was deduced to be 3 using the reversed octant rule.