Skeletal reorganization of enynes catalyzed by InCl3
Skeletal reorganization of enynes catalyzed by InCl3
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DOI：
10.1021/ol060606d
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发表时间：
2006-05-11
期刊：
影响因子：
5.2
通讯作者：
Chatani, N
中科院分区：
文献类型：
--
作者：
Miyanohana, Y;Chatani, N
烯炔的骨架重组是在InCl3催化剂的存在下实现的。具有末端乙酰基的烯炔以立体专一性的方式进行反应生成1-乙烯基环烯，含有烷基的烯炔在乙酰基末端碳上的反应导致一种新型的骨架重组得到1-烯丙基环烯，其形成涉及C-C双键和三键的双裂解。
The skeletal reorganization of enynes is achieved by the presence of InCl3 as the catalyst. The reaction of enynes having a terminal acetylenic moiety proceeds in a stereospecific manner to give 1-vinylcycloalkenes, The reaction of enynes containing an alkyl group on the acetylenic terminal carbon resulted in a new type of skeletal reorganization to give 1-allylcycloalkenes, formation of which involves a double cleavage of the C-C double bond and the triple bond.