Copper-Catalyzed Decarboxylative Cycloaddition of Propiolic Acids, Azides, and Arylboronic Acids: Construction of Fully-Substituted 1,2,3-Triazoles.
Copper-Catalyzed Decarboxylative Cycloaddition of Propiolic Acids, Azides, and Arylboronic Acids: Construction of Fully-Substituted 1,2,3-Triazoles.
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DOI：
10.1021/acs.joc.9b03285
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发表时间：
2020-01
期刊：
影响因子：
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通讯作者：
Xiang-xiang Wang;Yangchun Xin;Yi Li;Wen-Jin Xia;Bin Zhou;Ruirong Ye;Ya-Min Li
中科院分区：
文献类型：
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作者：
Xiang-xiang Wang;Yangchun Xin;Yi Li;Wen-Jin Xia;Bin Zhou;Ruirong Ye;Ya-Min Li
介绍了一种铜催化的丙炔酸、叠氮化物和芳基硼酸的脱羧环加成反应。本反应提供了一种从容易获得的起始原料合成各种完全取代的1，2，3-三唑的有效和方便的方法。提出了一种可能的机制。
A copper-catalyzed decarboxylative cycloaddition of propiolic acids, azides, and arylboronic acids is described. The present reaction provides an efficient and convenient method for the synthesis of various of fully-substituted 1,2,3-triazoles from readily available starting materials. A possible mechanism is proposed.