Electrochemical Degradation of Phenol and Resorcinol Molecules through the Dissolution of Sacrificial Anodes of Macro-Corrosion Galvanic Cells
Electrochemical Degradation of Phenol and Resorcinol Molecules through the Dissolution of Sacrificial Anodes of Macro-Corrosion Galvanic Cells
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DOI：
10.3390/w10060770
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发表时间：
2018-06
期刊：
影响因子：
3.4
通讯作者：
B. Pierożyński;G. Piotrowska
中科院分区：
文献类型：
--
作者：
B. Pierożyński;G. Piotrowska
This paper reports on the processes of phenol and resorcinol electrodegradation carried-out through continuous anodic dissolution of aluminum alloy and carbon steel sacrificial anodes for artificially aerated Cu-Al alloy and Cu-Fe-based galvanic (macro-corrosion) cells and synthetically prepared wastewater solutions. Electrochemical experiments were carried-out by means of a laboratory size, PMMA (Poly-methyl methacrylate)-made electrolyser unit, where significant degrees of phenol (10–89%) and resorcinol (13–37%) decomposition were obtained and visualized through the respective chemical/spectroscopy analyses. In addition, quantitative determination of phenol, as well as resorcinol (and possible electrodegradation products) for the selected experimental conditions was performed by means of instrumental high-performance liquid chromatography/mass spectrometry analysis.
