Activation of a cyclobutanone carbon-carbon bond over an aldehyde carbon-hydrogen bond in the rhodium-catalyzed decarbonylation
Activation of a cyclobutanone carbon-carbon bond over an aldehyde carbon-hydrogen bond in the rhodium-catalyzed decarbonylation
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DOI：
10.1246/cl.2006.288
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发表时间：
2006-03-05
影响因子：
1.6
通讯作者：
Murakami, M
中科院分区：
文献类型：
--
作者：
Matsuda, T;Shigeno, M;Murakami, M
铑（I）-N-杂环卡宾配合物实现了环丁酮的高收率脱羰反应，选择性地得到环丙烷。使用该催化剂，具有醛部分的环丁酮经历酮羰基的化学选择性脱羰基，其中酮羰基保持完整。
A rhodium(I)-N-heterocyclic carbene complex achieved a high-yield decarbonylation reaction of cyclobutanones to selectively afford cyclopropanes. With this catalyst, a cyclobutanone having an aldehyde moiety underwent chemoselective decarbonylation of the ketonic carbonyl group with the aldehydic carbonyl group left intact.