ASYMMETRIC ADDITION OF (E)-CROTYL-TRANS-2,5-DIMETHYLBOROLANES AND (Z)-CROTYL-TRANS-2,5-DIMETHYLBOROLANES TO ALDEHYDES
ASYMMETRIC ADDITION OF (E)-CROTYL-TRANS-2,5-DIMETHYLBOROLANES AND (Z)-CROTYL-TRANS-2,5-DIMETHYLBOROLANES TO ALDEHYDES
复制标题
DOI：
10.1021/jo00230a043
复制
发表时间：
1987-10-16
影响因子：
3.6
通讯作者：
MASAMUNE, S
中科院分区：
文献类型：
--
作者：
GARCIA, J;KIM, BM;MASAMUNE, S
同手性(E)-和(Z)-丁基-反式-2,5-二甲基硼烷与醛的反应使同丙烯醇具有优异的非映和对映选择性。
Reactions of homochiral (E)- an (Z)-crotyl-trans-2,5-dimethylborolanes with aldehydles proceed to provide homoallylic alcohols with excellent diastereo- and enantioselectivity.