Silver insertion mode in β-AgxV2O5 tunnel structure
Silver insertion mode in β-AgxV2O5 tunnel structure
复制标题
β-AgxV2O5隧道结构中的银插入模式
DOI：
10.1107/s0108270193007802
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发表时间：
1994
期刊：
影响因子：
--
通讯作者：
J. Galy
中科院分区：
文献类型：
--
作者：
E. Deramond;J. Savariault;J. Galy
钒酸银的β-Ag x V 2 O 5相具有很大的均匀性范围，0. 29 ≤x≤ 0. 41;其晶体结构的（V 2 O 5）n网络是钒氧化物青铜的典型β相，其氧化隧道沿着延伸[010]。Ag原子以一种新颖的方式嵌入，分布在两个不同的晶体学位置上，这解释了β相的理论边界极限x=0.33的超越
The β-Ag x V 2 O 5 phase of silver vanadate has a large homogeneity range, 0.29≤x≤0.41; the (V 2 O 5 ) n network of its crystal structure is typical of the β phase of the vanadium oxide bronzes with its oxygenated tunnels running along [010]. Ag atoms are inserted in a novel manner, being distributed onto two distinct crystallographic sites, which explains the overstepping of the theoretical boundary limit of the β phases, x=0.33