Facile Fabrication of Photochromic Dye–Conducting Polymer Core–Shell Nanomaterials and Their Photoluminescence

Facile Fabrication of Photochromic Dye–Conducting Polymer Core–Shell Nanomaterials and Their Photoluminescence
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DOI:
10.1002/adma.200304819
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发表时间:
2003-06
期刊:
影响因子:
29.4
通讯作者:
Jyongsik Jang;Joon Hak Oh
Jyongsik Jang;Joon Hak Oh
中科院分区:
材料科学1区
文献类型:
--
作者:
Jyongsik Jang;Joon Hak Oh

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以微乳液胶束为纳米反应器,制备了光致变色染料(芘)-导电聚合物(聚吡咯)核壳纳米材料。由于相分离和芘晶体的堆积限制,芘的吸附状态在很宽的范围内可调,且芘的负载量很小。这种方法提供了一种简便的方法来控制有机染料的发射,也提出了一个新的概念,纳米杂化电子器件。
Photochromic dye (pyrene)–conducting polymer (polypyrrole) core–shell nanomaterialswere fabricated using microemulsion micelles as nanoreactors. The adsorption state of pyrene was tunable over a wide range with a small pyrene loading because of the phase separation and the packing constraints of the pyrene crystal. This methodology provides a facile way to control the emission of organic dyes, and also presents a new concept of nanohybrids for electronic devices.