Solution-processed vanadium oxides as a hole-transport layer for Sb2Se3 thin-film solar cells
Solution-processed vanadium oxides as a hole-transport layer for Sb2Se3 thin-film solar cells
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DOI：
10.1016/j.solener.2021.11.009
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发表时间：
2022-01
期刊：
影响因子：
6.7
通讯作者：
Al-Robaidi Amin;Liping Guo;S. Vijayaraghavan;Dian Li;Xiaomeng Duan;Harigovind G. Menon;Jacob Wall;Subhadra Gupta;Mark Ming-Cheng Cheng-Mark-Ming-Cheng-Cheng-1399248973;Yufeng Zheng;Lin Li;Feng Yan
中科院分区：
文献类型：
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作者：
Al-Robaidi Amin;Liping Guo;S. Vijayaraghavan;Dian Li;Xiaomeng Duan;Harigovind G. Menon;Jacob Wall;Subhadra Gupta;Mark Ming-Cheng Cheng-Mark-Ming-Cheng-Cheng-1399248973;Yufeng Zheng;Lin Li;Feng Yan
硒化锑（Sb2Se3）由于其优异的光电性能，是一种很有前途的太阳能电池吸收材料。然而，由于其开路电压（VOC）低，sb2se3太阳能电池的电流性能远低于其理论值（~ 32%）。在本文中，我们证明了无机钒氧化物（VOx）作为sb2se3太阳能电池的空穴传输层（HTL），通过改善vocs来提高效率。在这里，通过三异丙氧钒(V)氧化物的分解，溶液处理的vox沉积在由紧密间隔升华（CSS）制备的sb2se3吸收层上。使用voxhtml，可以显著提高内置电压（Vbi），从而改善sb2se3太阳能电池器件的voc。因此，该设备的效率从平均5.5%提高到6.3%。
Antimony selenide (Sb2Se3) is a promising light absorber material for solar cells because of its superior photovoltaic properties. However, the current performance of the Sb2Se3solar cell is much lower than its theoretical value (∼32%) due to its low open-circuit voltage (VOC). In this paper, we have demonstrated inorganic vanadium oxides (VOx) as a hole transport layer (HTL) for Sb2Se3solar cells to enhance efficiency through theVOCimprovement. Here, a solution-processed VOxthrough the decomposition of the triisopropoxyvanadium (V) oxide is deposited on the Sb2Se3absorber layer prepared by close-spaced sublimation (CSS). With VOxHTL, the built-in voltage (Vbi) is significantly increased, leading to improvedVOCfor the Sb2Se3solar cell devices. As a result, the efficiency of the device increases from an average efficiency of 5.5% to 6.3% with the VOx.