In situ formation of N,O-bidentate ligand via the hydrogen bond for highly efficient Suzuki reaction of aryl chlorides.

In situ formation of N,O-bidentate ligand via the hydrogen bond for highly efficient Suzuki reaction of aryl chlorides.
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DOI:
10.1039/b925144h
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发表时间:
2010-04
影响因子:
4.9
通讯作者:
Weibo Yang;Chongxing Liu;J. Qiu
Weibo Yang;Chongxing Liu;J. Qiu
中科院分区:
化学2区
文献类型:
--
作者:
Weibo Yang;Chongxing Liu;J. Qiu

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报道了一种高效的Pd(OAc)2催化氯代芳烃的Suzuki反应,该反应是在溶剂中通过氢键原位形成的N,O-双齿配体的作用下进行的.
A highly efficient protocol for the Pd(OAc)2-catalyzed aerobic Suzuki reaction of aryl chlorides is reported, which is proposed to be promoted by the N,O-bidentate ligand formed in situ via the hydrogen bond of solvents.