Recent Progress in Chemistry of SF5-Olefins and Aliphatic Organic Compounds
Recent Progress in Chemistry of SF5-Olefins and Aliphatic Organic Compounds
复制标题
SF5-烯烃和脂肪族有机化合物化学研究新进展
DOI：
10.1142/9781786347336_0005
复制
发表时间：
2020
期刊：
影响因子：
--
通讯作者：
G.-V. Röschenthaler
中科院分区：
文献类型：
--
作者：
M. Ponomarenko;G.-V. Röschenthaler
含氟化合物在当今生活中的影响越来越大，这也适用于五氟-λ-硫烷基（SF 5）有机化合物，因为它们在先进材料、药物和农用化学品中具有潜力。SF 5-基团被认为是更好的吸电子基团，1-3是更亲脂的基团，并且是三氟甲基官能团的更大的替代物。合成方法的新发展将增加SF 5构件的供应。SF 5-有机化合物化学的重大进展的指标之一是最近总结该化学的年度进展的综合评论的数量。4-15然而，农业和药物化学的最新技术目前
There is a growing impact of fluorine-containing compounds in today's life which applies also to pentafluoro-λ-sulfanyl (SF5) organyls with respect to their potential in advanced materials, pharmaceuticals, and agrochemicals. The SF5-group is considered a better electron withdraw-ing, 1-3 a more lipophilic, and bulkier replacement of the trifluoromethyl function. New developments of synthetic methodologies will increase the availability of the SF5-building blocks. One of the indicators of the significant progress in the chemistry of SF5-organic compounds is the number of recent comprehensive reviews summarizing annual advances of this chemistry. 4-15 However, the state-of-the-art in agricultural and medicinal chemistry is currently