Assignment of the infrared spectrum for the ethyl radical

Assignment of the infrared spectrum for the ethyl radical
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乙基的红外光谱分配

DOI:
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发表时间:
1982
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影响因子:
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通讯作者:
M. Dupuis
M. Dupuis
中科院分区:
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文献类型:
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作者:
J. Pacansky;M. Dupuis

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在Ar基质中,通过相应的二丙酰基过氧化氢的光解,观察到了CH/sub3/CH/sub2/、CH/sub3/Cd/sub2/、Cd/sub3/CH/sub2/和Cd/sub3/Cd/sub2/的红外光谱。同位素物种的光谱与详细的从头计算相结合,为指认提供了基础。分析揭示了光谱特征,这些特征显然是未配对电子的表现。
The infrared spectra of CH/sub 3/CH/sub 2/, CH/sub 3/CD/sub 2/, CD/sub 3/CH/sub 2/, and CD/sub 3/CD/sub 2/ have been observed in argon matrices by photolysis of the corresponding dipropionyl peroxides. The spectra of the isotopic species coupled with detailed ab initio calculations have provided the basis for an assignment. The analysis has revealed the spectral features that are clearly a manifestation of the unpaired electron.