Assignment of the infrared spectrum for the ethyl radical
Assignment of the infrared spectrum for the ethyl radical
复制标题
乙基的红外光谱分配
DOI:
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发表时间:
1982
期刊:
影响因子:
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通讯作者:
M. Dupuis
中科院分区:
文献类型:
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作者:
J. Pacansky;M. Dupuis
The infrared spectra of CH/sub 3/CH/sub 2/, CH/sub 3/CD/sub 2/, CD/sub 3/CH/sub 2/, and CD/sub 3/CD/sub 2/ have been observed in argon matrices by photolysis of the corresponding dipropionyl peroxides. The spectra of the isotopic species coupled with detailed ab initio calculations have provided the basis for an assignment. The analysis has revealed the spectral features that are clearly a manifestation of the unpaired electron.