C(aryl)-C(alkyl) bond formation from Cu(ClO4)2-mediated oxidative cross coupling reaction between arenes and alkyllithium reagents through structurally well-defined Ar-Cu(III) intermediates.
C(aryl)-C(alkyl) bond formation from Cu(ClO4)2-mediated oxidative cross coupling reaction between arenes and alkyllithium reagents through structurally well-defined Ar-Cu(III) intermediates.
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DOI：
10.1039/c2cc35067j
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发表时间：
2012-08
影响因子：
4.9
通讯作者：
Zu‐Li Wang;Liang Zhao;Mei-Xiang Wang
中科院分区：
文献类型：
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作者：
Zu‐Li Wang;Liang Zhao;Mei-Xiang Wang
由azacalix[1]芳烃[3]吡啶与Cu(ClO(4))(2)·6H(2)O在好氧条件下定量制备的Ar-Cu（III）中间体稳定且结构明确，在温和条件下与多种烷基锂试剂顺利反应形成C（芳基）-C（烷基）键。
The stable and structurally well-defined Ar-Cu(III) intermediates, that are prepared almost quantitatively from the reaction of azacalix[1]arene[3]pyridines with Cu(ClO(4))(2)·6H(2)O under aerobic conditions, reacted smoothly with a number of alkyllithium reagents under mild conditions to form C(aryl)-C(alkyl) bonds.