A review of linear carbon chains

A review of linear carbon chains
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线性碳链综述

DOI:
10.1016/j.cclet.2020.03.019
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发表时间:
2020-07
影响因子:
9.1
通讯作者:
Shi Lei
Shi Lei
中科院分区:
化学1区
文献类型:
--
作者:
Zhang Kan;Zhang Yifan;Shi Lei

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线性碳链(linear carbon chains,LCC)是碳的一维sp1杂化同素异形体。LCC非常不稳定:LCC越长,材料越不稳定。因此,合成长LCC是一个很大的挑战。虽然对短LCC的研究,例如,多炔,可以追溯到18世纪,与碳的其他同素异形体相比,LCC仍然不为人所知,例如,富勒烯、碳纳米管和石墨烯。因此,介绍LCCs的最新研究进展,对于引起纳米碳和纳米材料界的更多关注具有重要意义。从理论上预测了各种优异的性能。在实验上,成功地合成了不同长度、不同形态的LCC。本文从理论和实验两个方面综述了多炔液晶催化剂的研究进展。最后,指出了材料进一步研究的方向.
Linear carbon chains (LCCs) are a one-dimensional sp1-hybridized allotrope of carbon. LCCs are extremely unstable: The longer the LCCs, the less stable the materials. Thus, it is a big challenge to synthesize long LCCs. Although the research on the short LCCs,e.g., polyynes, can be traced back to the 18th, LCCs are still not well-known compared to other allotropes of carbon,e.g.,fullerenes, carbon nanotubes and graphene. Therefore, introducing recent progress on LCCs is of great significance to draw more attention in the community of nanocarbons as well as nanomaterials in general. Theoretically, various excellent properties have been predicted. Experimentally, LCCs with different length in many kinds of forms have been successfully synthesized. In this review, we summarized recent studies of polyynic LCCs from both theoretical and experimental aspects. Also, perspectives are highlighted to point out the further investigations of the materials.
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