Preliminary communication: Magnetic-field-induced Freedericksz transition of a planar aligned liquid crystal doped with porphyrinatozinc(II): influence of the substituent of the porphyrin ring

Preliminary communication: Magnetic-field-induced Freedericksz transition of a planar aligned liquid crystal doped with porphyrinatozinc(II): influence of the substituent of the porphyrin ring
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DOI:
10.1080/026782900202741
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发表时间:
2000-04
期刊:
影响因子:
2.2
通讯作者:
Tao Li;X. Ying;Long‐pei Shi;Jin-wang Huang;Ziyang Lin;Jue Shi;L. Ji
Tao Li;X. Ying;Long‐pei Shi;Jin-wang Huang;Ziyang Lin;Jue Shi;L. Ji
中科院分区:
化学3区
文献类型:
--
作者:
Tao Li;X. Ying;Long‐pei Shi;Jin-wang Huang;Ziyang Lin;Jue Shi;L. Ji

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研究了掺杂1.0wt%抗磁性卟啉锌(II)的平面取向向列相液晶的磁场诱导Fredericksz相变。结果表明,与纯5CB相比,掺入1.0wt%不同取代基苯环上的Zn(II)TPP-5,10,15,20-tetraphenyl-porphyrinatozinc(II)-衍生物的5CB具有陡峭的Fredericksz转变曲线,临界磁场显著降低。
The magnetic-field-induced Freedericksz transition of a planar aligned nematic liquid crystal doped with 1.0 wt % of a diamagnetic porphyrinatozinc(II) has been studied. It was observed that 5CB doped with 1.0 wt % of derivatives of Zn(II)TPP-5,10,15,20-tetraphenyl-porphyrinatozinc(II) - which have different substituents in one phenyl ring display sharp Freedericksz transition curves and dramatically decrease the critical magnetic field compared with pure 5CB.