Development of Activator-free Iron Pincer Complexes for Alkene Hydrosilylation and Elucidation of Its Activation Mechanism
Development of Activator-free Iron Pincer Complexes for Alkene Hydrosilylation and Elucidation of Its Activation Mechanism
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DOI：
10.1246/cl.190521
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发表时间：
2019-08
影响因子：
1.6
通讯作者：
M. Kamitani;H. Kusaka;H. Yuge
中科院分区：
文献类型：
--
作者：
M. Kamitani;H. Kusaka;H. Yuge
考察了二卤化铁络合物对烯烃硅氢加成反应的活化作用，沿着氢硅烷的氢化反应。活化剂与铁试剂反应制得的预催化剂具有良好的催化活性。
Activation of iron dihalide complex for hydrosilylation of alkene was examined along with the disproportionation of hydrosilane. The pre-catalyst prepared in the reaction of activators with iron di...