Recent progress in lead-free perovskite (-like) solar cells

Recent progress in lead-free perovskite (-like) solar cells
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DOI:
10.1016/j.mtener.2018.03.001
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发表时间:
2018-06
影响因子:
9.3
通讯作者:
Qiaohui Zhang;Hungkit Ting;Shiyuan Wei;D. Huang;Cuncun Wu;Weihai Sun;Bo Qu;Shufeng Wang;
Qiaohui Zhang;Hungkit Ting;Shiyuan Wei;D. Huang;Cuncun Wu;Weihai Sun;Bo Qu;Shufeng Wang;
中科院分区:
材料科学3区
文献类型:
--
作者:
Qiaohui Zhang;Hungkit Ting;Shiyuan Wei;D. Huang;Cuncun Wu;Weihai Sun;Bo Qu;Shufeng Wang;

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Organic-inorganic hybrid perovskite solar cells (SCs) have emerged as one of the most promising contenders to traditional silicon solar cells, due to their active layers outstanding photoelectric properties, such as appropriate direct bandgap, balanced high carrier mobility and long carrier diffusion length, the identified power conversion efficiency (PCE) has reached to 22.7%. But the toxic lead, a key component in the archetypical light harvesting material, is a large obstacle to commercialization. Herein, we reviewed the recent progress in lead-free perovskite (-like) SCs according to the valent difference of metal ions in absorber material, e.g., bivalent (Sn2+, Ge2+, Cu2+, Sr2+), trivalent (Bi3+, Sb3+), tetravalent (Sn4+) and hybrid valent (e.g. Ag+and Bi3+). Finally, we gave an outlook on the tactic to achieve high performance lead-free perovskite (-like) SCs.