Labdane-type diterpene dialdehyde, pungent principle of myoga, Zingiber mioga Roscoe

Labdane-type diterpene dialdehyde, pungent principle of myoga, Zingiber mioga Roscoe
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DOI:
10.1271/bbb.66.2698
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发表时间:
2002-12-01
影响因子:
1.6
通讯作者:
Osawa, T
Osawa, T
中科院分区:
工程技术4区
文献类型:
--
作者:
Abe, M;Ozawa, Y;Osawa, T

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根据其物理和光谱性质(MS、NMR、IR和UV),鉴定了myoga(米奥加)的辛辣成分为(E)-8 β(17)-epoxylabd-12-ene-15,16-dial(米奥加醛)。Galanal A和B,分离以及miogadial,没有辛辣的味道。减少miogadial也无味。辛烯醛的辛味主要取决于辛烯醛中不饱和的1,4-二醛基。
The pungent principle of myoga (Zingiber mioga Roscoe) was identified as (E)-8beta(17)-epoxylabd-12-ene-15,16-dial (miogadial) on the basis of its physical and spectroscopic properties (MS, NMR, IR, and UV). Galanal A and B, isolated as well as miogadial, had no hot taste. Reduced miogadial also was tasteless. The pungency of miogadial depended on the presence of alphabeta-unsaturated-1,4-dialdehyde group.