Reply to "Comment on `Superconductivity in electron-doped layered TiNCl with variable interlayer coupling' "
Reply to "Comment on `Superconductivity in electron-doped layered TiNCl with variable interlayer coupling' "
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DOI：
10.1103/physrevb.90.186502
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发表时间：
2014-11
影响因子：
3.7
通讯作者：
S. Zhang;Masashi Tanaka;S. Yamanaka
中科院分区：
文献类型：
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作者：
S. Zhang;Masashi Tanaka;S. Yamanaka
我们详细地研究了电子掺杂型TiNCl(FeOCl正交型)，发现各种有机溶剂分子与碱原子共插层时，其18.0K的转变温度随着层间距的增大而单调下降。我们的结论是，这类实验结果暗示了层间库仑耦合的重要性。Rev.B86,024516(2012年)]，这与以前在电子掺杂形式的氯化锆和氯化氢中发现的行为形成了强烈的对比。在他们的评论中，Harshman和Fiory[Phys.Rev.B90,186501(2014年)]讨论了一个带有远程库仑散射的详细模型来缩放优化的${T}_{c}$，这与我们的结论是一致的。
We have studied the electron-doped $\ensuremath{\alpha}$-form TiNCl (FeOCl orthorhombic type) in detail and have found the transition temperature ${T}_{c}$ of 18.0 K decreases monotonically with increasing the interlayer spacing $d$ upon co-intercalation of various kinds of organic solvent molecules with alkali atoms. We conclude that such kinds of experimental results imply the importance of interlayer Coulomb coupling [Phys. Rev. B 86, 024516 (2012)], which is a strong contrast to the behavior previously found in the electron doped $\ensuremath{\beta}$-form ZrNCl and HfNCl. In their Comment, Harshman and Fiory [Phys. Rev. B 90, 186501 (2014)] discuss a detailed model with remote Coulomb scattering to scale the optimized ${T}_{c}$, which is consistent with our conclusion.