Heck couplings at room temperature in nanometer aqueous micelles
Heck couplings at room temperature in nanometer aqueous micelles
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DOI：
10.1021/ol702755g
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发表时间：
2008-04-03
期刊：
影响因子：
5.2
通讯作者：
Taft, Benjamin R.
中科院分区：
文献类型：
--
作者：
Lipshutz, Bruce H.;Taft, Benjamin R.
非离子两亲物，如Triton X-100或基于维生素E的PTS，两者都在水中形成纳米胶束，在常温下促进非水溶性伙伴的Heck交叉偶联。这些是在室温下在水(作为唯一的溶剂)中进行的Heck反应的第一个例子。
A nonionic amphiphile such as Triton X-100 or the vitamin E-based PTS, both of which form nanomicelles in water, promotes Heck cross- couplings of non-water-soluble partners at ambient temperatures. These are the first examples of Heck reactions conducted in water (as the only solvent) at room temperature.