Halogen-bonded liquid crystals of 4-alkoxystilbazoles with molecular iodine: a very short halogen bond and unusual mesophase stability
Halogen-bonded liquid crystals of 4-alkoxystilbazoles with molecular iodine: a very short halogen bond and unusual mesophase stability
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DOI：
10.1039/c3cc41227j
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发表时间：
2013-01-01
影响因子：
4.9
通讯作者：
Bruce, Duncan W.
中科院分区：
文献类型：
--
作者：
McAllister, Linda J.;Praesang, Carsten;Bruce, Duncan W.
分子碘与烷氧基芪唑的配合物是具有异常高的中间相稳定性的液晶，基于分子间I中心点I接触。尝试用溴制备类似的络合物导致了意想不到的亲电取代产物。
Complexes of molecular iodine with alkoxystilbazoles are liquid crystals with unusually high mesophase stability, predicated on an intermolecular I center dot center dot center dot I contact. Attempts to prepare analogous complexes with bromine led to an unexpected electrophilic substitution product.