Direct observation of the labile imine formation through single-crystal-to-single-crystal reactions in the pores of a porous coordination network
Direct observation of the labile imine formation through single-crystal-to-single-crystal reactions in the pores of a porous coordination network
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DOI：
10.1021/ja7111564
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发表时间：
2008-02-06
影响因子：
15
通讯作者：
Fujita, Makoto
中科院分区：
文献类型：
--
作者：
Haneda, Tsuyoshi;Kawano, Masaki;Fujita, Makoto
我们报告了一种原位观察由单晶到单晶化学反应产生的不稳定物质的方法。我们成功地在均匀的形成和直接观察不稳定的亚胺在3-D多孔配位网络的孔隙与醛提供的客人交换。此外，我们发现了显着的动态运动的主体框架的一部分，通过改变醛。
We report an approach to in situ observation of unstable species produced by a single-cystal-to single-crystal chemical reaction. We succeeded in uniform formation and the direct observation of unstable imines in pores of a 3-D porous coordination network with aldehydes provided by guest exchange. Moreover, we found the remarkable dynamic motion of a part of the host framework by changing aldehydes.