Rational Construction of Wide Coordination Space and Control of Adsorption Properties in One-Dimensional Cu(II) Coordination Polymer
Rational Construction of Wide Coordination Space and Control of Adsorption Properties in One-Dimensional Cu(II) Coordination Polymer
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DOI：
10.1021/cg2001392
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发表时间：
2011-05
影响因子：
3.8
通讯作者：
S. Noro;Katsuo Fukuhara;K. Kubo;Takayoshi Nakamura
中科院分区：
文献类型：
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作者：
S. Noro;Katsuo Fukuhara;K. Kubo;Takayoshi Nakamura
合理合成了轴向位点具有宽配位空间的一维Cu(II)配位聚合物{[Cu(bpetha)(2,2′-bpy)(MeOH)]·2PF6}n (bpetha =1,2-双(4-吡啶基)乙烷;2,2′-bpy =2,2′-联吡啶)并进行了晶体学表征，其中 [Cu(2,2'-bpy)] 单元通过 bpetha 配体桥接，形成一维之字形链，对 EtOH、MeOH 和 H2O 蒸汽表现出平滑的吸附。
A one-dimensional Cu(II) coordination polymer {[Cu(bpetha)(2,2′-bpy)(MeOH)]·2PF6}n (bpetha =1,2-bis(4-pyridyl)ethane; 2,2′-bpy =2,2′-bipyridine) with wide coordination space at the axial site was rationally synthesized and crystallographically characterized, in which [Cu(2,2′-bpy)] units are bridged by bpetha ligands, forming a one-dimensional zigzag chain that shows smooth adsorption for EtOH, MeOH, and H2O vapors.