Metal-bound chlorine often accepts hydrogen bonds
Metal-bound chlorine often accepts hydrogen bonds
复制标题
DOI：
10.1039/a709014e
复制
发表时间：
1998-03-21
影响因子：
4.9
通讯作者：
Orpen, AG
中科院分区：
文献类型：
--
作者：
Aullón, G;Bellamy, D;Orpen, AG
6624晶体学特征的氢键含有M-Cl，C-Cl或Cl-和HO或HN基团的分析表明，M-Cl部分是良好的，各向异性的氢键受体形成的氢键长度类似的氯阴离子，而C-Cl部分是非常差的氢键受体。
Analysis of 6624 crystallographically characterised hydrogen bonds containing M-Cl, C-Cl or Cl- and either HO or HN groups show that M-Cl moieties are good, anisotropic hydrogen-bond accepters forming hydrogen bonds similar in length to those of the chloride anion, while C-Cl moieties are very poor hydrogen-bond accepters.