Lewis acid-promoted imine synthesis by the insertion of isocyanides into C-H bonds of electron-rich aromatic compounds.
Lewis acid-promoted imine synthesis by the insertion of isocyanides into C-H bonds of electron-rich aromatic compounds.
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DOI：
10.1021/ol071314v
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发表时间：
2007-07
期刊：
影响因子：
5.2
通讯作者：
Mamoru Tobisu;S. Yamaguchi;N. Chatani
中科院分区：
文献类型：
--
作者：
Mamoru Tobisu;S. Yamaguchi;N. Chatani
报道了路易斯酸促进异氰酸酯插入芳香族C-H键的反应。含有一系列N-取代基的亚胺官能团可以以良好的产率直接引入富含电子的芳烃中。
The Lewis acid-promoted insertion of isocyanides into aromatic C-H bonds is reported. An imine functionality containing an array of N-substituents can be introduced directly into electron-rich aromatics in good yields.