Compatibilizing effect of a filler in binary polymer mixtures

Compatibilizing effect of a filler in binary polymer mixtures
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DOI:
10.1016/s0032-3861(98)00277-8
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发表时间:
1999-03-01
期刊:
影响因子:
4.6
通讯作者:
Lipatov, YS
Lipatov, YS
中科院分区:
化学2区
文献类型:
--
作者:
Nesterov, AE;Lipatov, YS

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讨论了两种可互溶或不互溶的聚合物与固体混合的热力学问题。理论上表明,在二元聚合物混合物中引入一种特殊的填充剂,提高了三元体系的热力学稳定性。填料的增容作用取决于两种聚合物之间混合自由能的变化,对于不相容的体系,这种影响是非常明显的。(C)1998由爱思唯尔科学有限公司出版。版权所有。
The thermodynamics of mixing of two miscible or immiscible polymers with a solid has been considered. It is shown theoretically that the introduction of a specific filler in binary polymer mixtures increases the thermodynamic stability of the ternary system. The compatibilizing effect of the filler depends on the change in free energy of mixing between the two polymers, the effect being mom pronounced for immiscible systems. (C) 1998 Published by Elsevier Science Ltd. All rights reserved.