Functional microporous materials of metal carboxylate: Gas-occlusion properties and catalytic activities
Functional microporous materials of metal carboxylate: Gas-occlusion properties and catalytic activities
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DOI：
10.1016/j.jssc.2005.07.009
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发表时间：
2005-08
影响因子：
3.3
通讯作者：
W. Mori;Tomohiko Sato;T. Ohmura;C. Kato;T. Takei
中科院分区：
文献类型：
--
作者：
W. Mori;Tomohiko Sato;T. Ohmura;C. Kato;T. Takei
对苯二甲酸铜（II）是第一个发现能够吸附气体的过渡金属络合物。该配合物开辟了吸附剂配合物化学的新领域。它被认为是构建微孔复合物的先导化合物。这个特定的系统已经扩展到其他同晶过渡金属，钼（II），钌（II，III）和铑（II）的衍生物的系统系列。这些具有开放骨架的配合物被广泛认为是非常有用的材料，用于催化，分子水平的分离和气体储存。
Copper(II) terephthalate is the first transition metal complex found capable of adsorbing gases. This complex has opened the new field of adsorbent complex chemistry. It is recognized as the lead complex in the construction of microporous complexes. This specific system has been expanded to a systematic series of derivatives of other isomorphous transition metals, molybdenum(II), ruthenium(II, III), and rhodium(II). These complexes with open frameworks are widely recognized as very useful materials for applications to catalysis, separation at molecular level, and gas storage.