Rhodium(III)-Catalyzed ortho-C-H Alkylation of 2-Arylbenzothiazoles and 2-Arylthiazoles with Potassium Alkyltrifluoroborates
Rhodium(III)-Catalyzed ortho-C-H Alkylation of 2-Arylbenzothiazoles and 2-Arylthiazoles with Potassium Alkyltrifluoroborates
复制标题
铑(III)催化的2-芳基苯并噻唑和2-芳基噻唑与烷基三氟硼酸钾的邻位C-H烷基化
DOI：
10.1055/s-0036-1588936
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发表时间：
2017
影响因子：
2.6
通讯作者：
Peng Yiyuan
中科院分区：
文献类型：
--
作者：
Ping Yuanyuan;Chen Zhaobin;Ding Qiuping;Peng Yiyuan
开发了一种通用且有效的Rh（III）催化的2-芳基苯并噻唑和2-芳基噻唑与烷基三氟硼酸钾的邻位C-H烷基化反应。本方法导致的烷基化2-芳基苯并噻唑和2-芳基噻唑的库的建设，产率高达99%。
A general and efficient Rh(III)-catalyzedortho-C–H alkylation of 2-arylbenzothizazoles and 2-arylthiazoles with potassium alkyltrifluoroborates has been developed. The present method leads to the construction of a library of alkylated 2-arylbenzothiazoles and 2-arylthiazoles with yields up to 99%.