CHIRAL SALEN MANGANESE COMPLEX ENCAPSULATED WITHIN ZEOLITE Y : A HETEROGENEOUS ENANTIOSELECTIVE CATALYST FOR THE EPOXIDATION OF ALKENES
CHIRAL SALEN MANGANESE COMPLEX ENCAPSULATED WITHIN ZEOLITE Y : A HETEROGENEOUS ENANTIOSELECTIVE CATALYST FOR THE EPOXIDATION OF ALKENES
复制标题
DOI：
10.1039/a701337j
复制
发表时间：
1997
影响因子：
4.9
通讯作者：
M. Sabater;A. Corma;A. Doménech;V. Fornés;H. García
中科院分区：
文献类型：
--
作者：
M. Sabater;A. Corma;A. Doménech;V. Fornés;H. García
在Y分子筛的超笼内制备了一种类似Jacobsen催化剂的手性（salen）Mn III配合物[salen：反式-(R，R)-1,2-双（水杨酸氨基）环己烷]，其催化活性与均相氯配合物非常相似。
A chiral (salen)Mn III complex [salen: trans-(R,R)-1,2-bis(salicylideneamino)cyclohexane] analogous to Jacobsen’s catalyst is prepared inside the supercages of zeolite Y, showing catalytic activity very similar to that of the chloride complex in the homogeneous phase.