Mechanical path to a photogenerated structure: ball milling-induced phase transition of a gold(I) complex
Mechanical path to a photogenerated structure: ball milling-induced phase transition of a gold(I) complex
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DOI：
10.1039/c5ce02565f
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发表时间：
2016-09
期刊：
影响因子：
3.1
通讯作者：
Kenta Sakurada;T. Seki;Hajime Ito
中科院分区：
文献类型：
--
作者：
Kenta Sakurada;T. Seki;Hajime Ito
球磨金（I）异氰化物配合物1的蓝色发光晶体1B诱导相变为黄色发光粉末1YG，其具有与先前报道的在光照射1B时获得的1Y相同的固体结构。这是机械刺激诱导相变为光可接近的结晶相的第一个例子。
Ball milling of blue-emitting crystal 1B of gold(I) isocyanide complex 1 induces a phase transition to yellow-emitting powder 1YG, which has the same solid structure as the previously reported 1Y obtained upon photoirradiation of 1B. This is the first example of mechanical stimulation inducing a phase change to a photo-accessible crystalline phase.