Dirhodium(II) Tetrakis(perfluorobutyrate)-Catalyzed 1,4-Hydrosilylation of α,β-Unsaturated Carbonyl Compounds
Dirhodium(II) Tetrakis(perfluorobutyrate)-Catalyzed 1,4-Hydrosilylation of α,β-Unsaturated Carbonyl Compounds
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DOI：
10.1248/cpb.54.1622
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发表时间：
2006-11
影响因子：
1.7
通讯作者：
M. Anada;Masahiko Tanaka;Kan Suzuki;H. Nambu;S. Hashimoto*
中科院分区：
文献类型：
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作者：
M. Anada;Masahiko Tanaka;Kan Suzuki;H. Nambu;S. Hashimoto*
探索了Dy(II)催化剂在α，β-不饱和酮和醛的1，4-硅氢化反应中的应用。四(全氟丁酸酯)，Rh2(PFB)4，证明是该工艺的首选催化剂，高产率地提供了相应的硅烯醇醚。
The use of dirhodium(II) catalysts in the 1,4-hydrosilylation of alpha,beta-unsaturated ketones and aldehydes was explored. Dirhodium(II) tetrakis(perfluorobutyrate), Rh2(pfb)4, proved to be the catalyst of choice for this process, providing the corresponding silyl enol ethers in high yields.