Separation of Enantiomeric Algal Pheromones and Related Hydrocarbons by Gas-Liquid Chromatography on Modified Cyclodextrins as Chiral Stationary Phases Biosynthetic Relevance of Racemic by-Products
Separation of Enantiomeric Algal Pheromones and Related Hydrocarbons by Gas-Liquid Chromatography on Modified Cyclodextrins as Chiral Stationary Phases Biosynthetic Relevance of Racemic by-Products
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以改性环糊精为手性固定相，通过气液色谱法分离对映体藻类信息素和相关碳氢化合物 外消旋副产物的生物合成相关性
DOI：
10.1002/hlca.19890720616
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发表时间：
1989
影响因子：
1.8
通讯作者：
Dieter G. Müller
中科院分区：
文献类型：
--
作者：
W. Boland;W. König;R. Krebber;Dieter G. Müller
采用气相色谱法，以修饰的环糊精为手性固定相，从两种海藻（Cutleria multifida和Chorda tomentosa）的信息素混合物中分离出烯烃多烯烯3和奥烯烯5对映体。该方法也适用于对映体烷基取代、烯基取代或烷基取代的环二烯和环戊烯的分离。对藻类信息素混合物外消旋副产物的生物合成提出了合理的解释。
The separation of the enantiomers of the olefinic hydrocarbons multifidene 3 and aucantene 5 from the pheromone blend of the two seaweeds Cutleria multifida and Chorda tomentosa is achieved by gas chromatography on modified cyclodextrins as chiral stationary phases. The method is also applicable for the separation of enantiomeric alkyl-, alkenyl- or alkynyl-substituted cyclooctadienes and cyclopentenes. A plausible rational is presented for the biosynthesis of racemic by-products of algal pheromone blends.